Putting the extra pair of speakers behind you is going to make it seem as if the music is both in front of you and behind you, because you are sending the same signal to both. It will fill the room with sound, if that is what you are wanting, but it is not going to realistically recreate the experience of listing to live music that way.
If all you want is the extra bass from the one set of speakers, you could put both pairs in front, one on top of the other, and you will not have the above problem. However, it will not work as well as one good pair of speakers, due to the fact that those pairs of speakers are not designed to work together, and so some frequencies will be overemphasized, and others will be underemphasized. It might, however, sound better than either pair of your current speakers on their own, depending on what they are, how, exactly, you position them, where exactly you sit, and your personal preferences.