Having Q750s all around would work great. I don't know if the extra $250 factored in speaker stands for the Q150s as part of the evaluation. Surround Speaker placement is a compromise in distance from any adjacent wall to distance from the prime listening area. For Bookshelves, or Floor Standing, it's about the same impact.
The amount of sound coming the surrounds will be relatively the same with either speaker, but the Q750s will do a better job of it. Most let the AVR determine the crossover points, and initially you should try the same. You'll have lots of time to tweak everything to your liking.