A less expensive solution is to just angle the current center up a bit. I did this just by stacking a couple rectangular pencil erasers under the front edge This solution is less than a couple dollars!
If not, I would strongly consider getting a Paradigm center that better matches your fronts, vice buying a ~$500 MSRP speaker from a different manufacturer. If your long range plan is to eventually put MLs all across your front sound stage, then your idea is a logical first step.
Buying one--no probelm other than cash!
Using one may be a problem. The Pio VSX94 is only spec'd to handle 6 ohm speakers (manual p. 19). I do not own a VSX94, so I can not say if it can
actually handle a 4 ohm speaker well or not.
There may be some VSX94 owners in this forum who could share if they have successfully run a 4 ohm speaker (preferably a Martin Logan) despite the Pio's spec'd rating.
Cheers,
XEagleDriver