Did you say what your new amp is?
I would probably hook the front three to the new amp, leaving channels 2 & 4 idle (to spread out the heat) and let the Marantz drive the 4 surround channels.
I am assuming you listen to music in stereo (so surrounds are not playing full music signal).
My thinking is that the front three are maybe 70% of the load and a 70/30 division is probably a rough estimate of amp capabilities (a lot of guess work to this, but wanted to explain the logic behind the guesswork).
In truth you can do about whatever you want and never come close to taxing your capabilities. That is the nice thing about over-kill (again I am assuming, you may have speakers that are especially demanding)!