Whoa there partner, you’re climbing the mountain before you overtake the hill.
First get the meter; doesn’t your receiver/pre/pro have a test tone generator?
If not, discs with test tones are easy enough; you can also download/burn specialty test tones.
I wouldn’t concern myself with any other gear at this point the goal here is to achieve the same levels in all speakers and then matching the subs levels to them, after that you can set them -/+ to your taste.
Lot easier to experiment when you can see results on the meter, i.e. moving subs for better blending, the extra 2/3 db on that center…etc. etc. etc….the meter is the biggest intelligent bang for the buck
Have fun with it.