Not sure what is up with the receiver since it's not at all like what Denon shows on their website. It clearly has a zone 2 output. I guess I would double check on that model number to make sure we are talking about the same product, maybe link to the product page.
That said, I would still get a multi-channel amp, and right now, this is the best deal I found...
https://www.ebay.com/itm/Sonance-Sonamp-1230-12-Channel-Power-Amplifier/273377460452?epid=66797633&hash=item3fa69100e4:g:rQEAAOSwhmtbS~WS&_sop=15&_sacat=0&_nkw=12+channel+amplifier&_from=R40&rt=nc&LH_TitleDesc=0|0
It's under $200 shipped and gives you 3 stereo zones (6 channels) with about 60 watts per channel. It's also built like a tank. It's not some cheap entry level garbage that will blow out after a year or two, but will last you for years and years, just as it likely has for the previous owner. I regularly buy off of eBay and have great results with a much higher quality product than you can buy for the same price.
You can then feed zone 2 from the amp into it or you can feed separate sources to it as you choose.
There are also audio distribution units with (and without) built in amplification from multiple companies out there. Those will be at least a couple grand to get.
The amp shown is the right way to get 3 completely separate zones of audio with dedicated amplification and you can feed the amp 3 individual sources if you want, or feed it a single source to share. With 3 dedicated sources that feature built in volume control and network control, then you control what is going on with each zone through your phone or tablet.