You're overcomplicating this.
Ideally, the two main speakers and your ears should form a perfect triangle.
Sometimes the room, and it's furnishings, has other ideas so you try to place them as close to this ideal as possible.
Once tou do that, you aim them towards your listening position. Adjust them both equally outwards, in small steps, until you get the best* sound.
Alternately, you could with them facing straight ahead and adjust them both equally inwards, in small seps, until you get the best* sound.
Take your time.
* "best", as always, is a personal preference. A laser does not have your ears.