For high quality playback . . .
You should consider adding a USB sound card that includes an optical or coax digital audio output for connection to the receiver.
Also, store the files on the PC in a lossless format like FLAC, or higher res MP3 files. This configuration is capable of much better quality then the iPod.
Another option would be the squeezebox 2/3 which includes high quality D/A converters for a good analog or digital connection to the receiver.