What each of them are for completely depends upon the person who wired the system. When I wire a system with 4 conductor wire, the red and black are for the right channel, red being positive black being negative. The white and green are for the left channel, white for positive, green for negative. I have no clue who wired the system or what their technique may have been. Try to find out who did the wiring and how it was done.
If that does not work, I would suggest a a DMM, a 1.5 volt AA battery, and an extra set of eyes.