I currently have an Onkyo TX-SR574. On the Onkyo website, it said that the amp is rated at 80 watts per channel at 8 ohms, and 100 watts per channel at 6 ohms. How do I change the ohms of my amp from 8 to 6? Also will this harm my amp or speakers in any way? Speakers are rated at 8 ohms
The impedance switch was discussed here a couple of years ago- it's there to prevent problems that shouldn't occur in the first place, due to designing things to hit a price point, rather than performance goals.
Power is a calculated value, based on the voltage and resistance of the speaker. The power supply can provide a certain amount of output, but if the speakers demand more, it may not be able to deliver. This switch limits the power supply's output, so it doesn't fail.
Even if you could select the output, adding 20W would barely be audible.
In light of your screen name, this would also apply to your guitar amp if it's solid state, but not exactly the same if you use tubes. Tube amps use an output transformer to couple the amp to the speakers and it has a rating, just like these amps but the effect of using the "wrong" speakers is somewhat different with tubes. You can use speakers that are one step to either side of "correct", but it's not good to go farther than that, so an amp rated for 8 Ohms can be used with 4, 8 or 16 Ohm speakers, but don't connect it to a Tweed Bassman cabinet that has original/similar speakers in its original wiring configuration- that will present a 2 Ohm load and your amp will NOT like that, at all- especially if you really crank it.
Some guitar amps have an impedance selector (Marshall, mostly) and this is only supposed to be changed when the amp is turned off- it changes the output transformer's connection, to allow the setting to match the speaker. McIntosh audio amplifiers have connections for the same reason.