Red & Black = Left (red = positive, black = negative)
White & Green = Right (white = positive, green = negative)
In a normal wiring hookup the above is correct.
To test, you can use a 9 volt battery and just touch the wires to it which will create a little bit of noise on each speaker. Shouldn't harm any of the speakers. You can also get a test tone producer, but that's a bit pricey if you don't own one already.
You probably should consider a speaker selector that does impedence matching or make sure the volume controls are impedence matching before hooking them all up!