Uncharted series easily among the best stories and best series on Playstation.
Last of Us and The Last of Us 2 easily the best stories period. The combat can be pretty challenging, but worth the effort. I might not say start here, but once you figure out if you like story type action games, these are excellent. Produced by the same studio as Uncharted. What they learned in Uncharted about story and gameplay trickled into Last of Us and vice versa. It makes both series great. Last of Us 2 won a ridiculous number of awards.
Red Dead Redemption 1 and 2 do have a solid story and great gameplay. Never got boring.
Horizon Zero Dawn has a deep story, but objectives get a little repetitive. The gameplay is excellent though. Control system, leveling and crafting system, all just work. I am actually replaying this ahead of the release of Horizon Forbidden West which comes out in 2 weeks.
Resident Evil 7 and 8. Very creepy. Very fun, always a fun series.
Death Stranding Director's Cut - this one is not for everyone. Slow, but very detailed and involving story. Less combat, more exploring. Probably my favorite game on PS5 so far, but I am a Hideo Kojima fan. Kojima games tend to come with some crazy ideas, but they are always very entertaining. A game about delivering packages in a post apocalyptic world? Sounds crazy right? It is strangely addictive and satisfying.