Is the back of the DVD (the "label side") scratched at all? It's easy to ruin the reflecting aluminum layer through that side as it's normally relatively thin.
I've yet to see a heat-damaged CD/DVD that wasn't pretty warped (left in a hot car for long enough in a bad CD case), but I'm sure weirder things have happened. Edit: on second thought, how would I know it was heat-damaged otherwise

? Very useful insight, I'm sure

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I've read a number of articles on proper back up online, normally relating to taking care of your CD-Rs and DVD-R/+Rs, but they might have some useful information on the unseen natural forces that could have damaged your DVD.