Bryan,
Depends on what you mean by "poly."
Different people have different definitions. If you are talking about semicylinders or semispheres, I would say they might could work, but you have to watch out for the comb-filtering associated with those types of devices.
What I've heard more success with in small room applications are random and pseudo-random devices. "Random" devices tend to be custom made. Either strategic use of bookcases, etc.; or actual custom-made devices. One of the better sounding recording rooms I've come across was in
a studio in Colorado where all the diffusors were custom-designed, random combinations of different sizes of wood strips. The best photos I could find on the net were
here. The band is pictured in front of the diffusors in several photos. (To the best of my knowledge, the diffusor design pictured was the studio owner's concept and design.) (Also, the very bottom pic is an RPG product from a different room or studio, I think.) (Anyway, you get the picture...
)