If your center channel is full range (running your center channel set to "large" in your receiver or prepro's settings), and you're looking for low frequency tracks to isolate your center channel; get the DVD-Audio version of Blue Man Group's first album
Audio: track 1 "Mandelgroove" and track 10 "Drumbone". The tubulum (long PVC pipe instrument with a deep sound) is isolated just in the center channel at a couple different points in these tracks as is the drumbone in track 10 (another PVC pipe instrument); and it's a very demanding reproduction. I think it sounds great but I'm biased cause I been around some of guys involved in the recording of this album (I was going to be a Blue Man, but a larger opportunity opened up, so ended my percussion days...

). Despite the bias, I still think it's a quality recording that's tough to reproduce at higher SPL levels unless you have plenty of power and speakerage, and it's the most demanding disc I have found for a center channel specifically.
High end frequency response demo... what type music do you like?
Norah Jones
Come Away With Me on SACD sounds great with an airy and open sound as does Diana Krall's CD
Girl in the Other Room, but if you don't like female vocalist jazz, then something else is in order... I just think those are two well recorded & engineered treble demo discs.
Regular movies are good; the center channel of course handles dialogue which in itself can tell you how your center's eq'd if voices sound too chesty (bassy) or tinny (too much treble). Post back what you are looking for music genre or movie wise.
Brad