Sergio,
Which source to use - loudspeaker or gunshot - depends on what the SLM can do. How does it (or, indeed, can it) determine RT?
For the size of room you're looking at, any RT equation and no RT equation are the answers. The room is a little too small (108 m³) to be considered statistically reverberant, except at high frequencies. Therefore, none of the equations are going to give numbers that jive with the measurements. However, for a general idea of how much absorption to add, any of the various equations should work fine. Sabine will be the easiest with which to work.
The calculated RTs will have to be adjusted to match the measurements. E.g., if the measurement says 2.4 s and the Sabine calc says 1.8 s, negative absorption should be "added" to the calcs to get the Sabine number up to 2.4 s. To get this to be as "accurate" as possible, make RT measurements at as many different points in the room as is reasonable. I would suggest between 4 and 6 different measurement points, none of which are too close to a room surface (1-1.5 m away, minimum).
Having said all that, calculations (and measurements) can be skipped completely, IMO. Assuming mostly hard surfaces to start with, 20-25% coverage of the walls and ceiling (roughly 22-27 m² for the room in question) with absorption - spread around and staggered - is always a good starting point for a rehearsal space. If that's not enough to get the desired room sound, keep treating with absorption and/or diffusion until it sounds good. It would be best to select broadband absorption (8 to 10 cm thick, minimum) and some "traps" for the corners.
HTH.