There is no evidence I have seen that bi-amping does anything. All the subjective claims aside, there are no double blind tests where setups are level matched…
If done properly, you won’t harm anything, however, to properly bi-amp, you should Not use your AVR, rather separate stereo amps. On every AVR I’ve looked at, the more amp channels you use, the less power available across each channel.
Regardless, it seems a silly thing to do for no proven gain.