To be able to put two amplifiers' power ratings head to head, they must be taken in the same manner. For example:
Amplifier A: 100 watts continuous x 2 (two channels driven as per FTC) at 8 ohms, 20hz-20khz +/- 0.5db, with < 0.07% thd
Amplifier B: 100 watts continuous x 2 (two channels driven as per FTC) at 8 ohms, 20hz-20khz +/- 0.5db, with < 0.08% thd
These amplifiers would essentially be identical in terms of performance
Now if the two amplifiers looked like this:
Amplifier A: 100 watts continuous x 2 (two channels driven as per FTC) at 8 ohms, 20hz-20khz +/- 0.5db, with < 0.07% thd
125 watts continuous x 2 (two channels driven as per FTC) at 4 ohms, 20hz-20khz +/- 0.5db, with < 0.1% thd
Amplifier B: 100 watts continuous x 2 (two channels driven as per FTC) at 8 ohms, 20hz-20khz +/- 0.5db, with < 0.08% thd
175 watts continuous x 2 (two channels driven as per FTC) at 4 ohms, 20hz-20khz +/- 0.5db, with < 0.1% thd
We are easily able to tell here that one amplifier (B) more capable at running lower impedance, or more reactive loads. We can also tell that it has more substantial reserve power for transients, i.e. dynamic power.
It is very difficult to judge performance of two amplifiers unless they are rated in the same manner. One can get an idea of an amplifier's performance from less telling specs, but it is difficult to say the least. Hopefully this helps you some.