Seating needs to come forwards and the seat on the side one of the other placed on riser at the back so it has clear view or LCR have clear sight line otherwise HF sounds will be blocked.
LCR need to go above the TV. Make a platform that extends the width of the room so that you can experiment freely moving the (matched LCR) the left right may need toeing in a small portion and angled downwards so clear HF sounds reach the seating.
You'd need to make false wall across the right side and fit in a door so the sound from the room won't drift out to other room and give odd sound cos the wall on the right in the dinning room is further away. You'll have bass issues of sort so need to put a false wall up and make the room as even as possible. Timber and plasterboard screws and handsaw hammer doesn't cost a lot just a few days of patience.
Fit more speakers small size bookshelves of same make/model and fit them above the window or ditch the window brick it up otherwise noise from outside will lower the noise floor and forcing you to play louder.
The arrays of surrounds on the sides with mono poles will give a cinema like surround and plenty bargains on ebay that can bought for under $100.00 or lower for pair and just keep buying. Place a number of them on the back wall, will give even surround coverage.
Your present placement idea will have snags. Idea of surround is to be surround otherwise the side surround placed further along the wall will not give you any what so ever sense of a sound object passing behind you with Dolby 424 matrix to Dolby 5.1 and 7.1 so place around x3 each side and each seat will get a good surround, otherwise I might as take all mine down and set up like a common 7.1 configuration and then I'd be kicking the seat.
If bricking the window up is not the option then have no fear. Mounting the speakers to the ceiling and spaced apart for each row on each side will also work with uniform surround around the seating. But check with small bookshelf mini speakers with a satisfactory sensitivity 88 or 89db with reasonable frequency response 60Hz 70Hz on the low end and use extra subs only for the surrounds to augment the low end to give the impression the surrounds can go down lower.
So move that seating forwards otherwise too far back unless you can achieve a decent wide enough left-to-right stereo from sound effects to dialogue panning, but really the further back you are the stereo image will become narrow its not the same as when sat in front row at large cinema.
I can't bend your arm and I'm not Mr. Wolf, at solving problems that will turn up driving a Lotus with a construction crew and have all this done in day.