Is the 80Hz rating at -3dB? If so, I'd set the crossover to 90Hz to start with. If you set it to 80Hz, then you'll have a dip for sure because your speakers will be rolling off at that point. The best setting will depend on your speakers, sub, and (to some extent) your room and placements.
You can download (or buy CDs that contain) test tone frequencies and run through those with an SPL meter to see if you're getting a dip around the crossover frequency.