Hopefully you don't take this the wrong way.
I advice you to get an inexpensive
measurement microphone to use with something like the free
REW - Room Acoustics Software. With this you can get some "hard" data as base for your decisions, and that includes various placements of your subwoofer, speakers as well as "Main Listening Position" (moving your desktop). Experimentation is key here.
You've not said
how you use your 5.1 system in your small room and
what type of content you listen to. That sad, from your pictures of placement of speakers and MLP (main listening position) there is likely no need for the centre speaker as the front left/right would probably work just fine, if not better. Do note if you like to play "loud" your present speakers likely will sound very bad i.e. harsh.
Perhaps getting a good pair of active monitors will turn out to have a much nicer sound that you are not happy with now?
In my small home office there are two 2.1 setups (stereo+subwoofer) and the monitors are really good, but also expensive. On the other hand, buying enough panels from GIK Acoustics is also expensive, and I rather put my money into an excellent pair of active monitors. Well, I did both, but I think my point stands on its own.
I had good discussions with GIK Acoustics three years ago before I bought my panels from them (in stages) but the better information you give them the better advice they can give, and that includes actual audio measurements.