Daisy chaining from the fronts? That's like permanent all-channel stereo. No surround channels. Not something I would recommend. The LS60 is strictly 2 channel. If you want discrete rear channels for movies you have to let the AVR do the decoding and feed the rears. That can be either with passive speakers via the amps or active speakers via the pre-outs.
Whether or not you benefit from rear channels depends on the room. LS60 on their own would still sound great and you don't need the expense of an AVR if the LS60 has enough inputs for your sources.
Make sure the rear speakers have the required inputs if you want to go surround. As mentioned, for centralized volume via your AVR remote, I am pretty sure you will have to use the analogue pre-outs on the AVR. While HDMI CEC may work from the AVR to LS60 for volume control, you can not daisy chain HDMI to control 2 pairs of speakers. The LSX II is designed to be used as a single pair of front speakers, like the LS60. Any digital sources will need the LSX II remote for volume control.
KEF does advertise that other KEF wireless speakers can link to the LS60 so that Airplay, Chromecast and Roon can stream to multiple speakers at once, but that is just for stereo music. There is no surround decoding, so you can not, for example, connect the TV to the LS60 and then wirelessly connect the LSX II for rear channels. So, to use the LSX II as rear channel speakers, you would need to use the 1/8" analogue auxiliary input, which means running cables from the AVR pre-outs to the LSX II and converting RCA to 1/8" TRS.
You would then want the LS60 and LSX II to be set at a fixed volume and use the AVR volume control to control the volume for all 4. What I don't know is whether the KEFs remember the last volume setting when powered off. If they do, then using 4 speakers via RCA connections should work. If the volume resets when powered off, then you would need to adjust the volume on each speaker each time you turn on the system.
That's my basic understanding of how it would work. Would be ideal if you could find someone who uses those speakers in a surround setup to confirm how it actually works.