Would my center be considered a main speaker?
No, maybe... you can't lump it all together.

As was said before, it comes down to the frequency response of the speaker. If your center is only rated down to, say, 57Hz, and you cross over at 60 or 80, you could potentially damage it. It would take loud hard extended bass, but it could happen.
You've got to know what your speaker specs are to really get it right.
Though I agree with Russ, you can't apply a blanket standard if your speakers don't match that criteria.
For your Left and Right, the 1 octave up was 94Hz, so experiment with 90 and 100 on that... listen to hear which sounds better, and if you are creating any low distortion in the woofers. If you are, set it higher.
If your center has smaller woofers than your L/R speakers, you probably need to set the Crossover higher, more in line with your surrounds.
I'd recommend maybe calling the company with the model numbers and see if they can advise you. That said, I wouldn't set that procenter at 40hz. 100, maybe.