There is obviously an advantage in tinning copper wires to prevent the metal from being tarnished. Copper oxide is a poor electric conductor.
IMO, we should always either tin the bare ends of wires to be connected for both low signal level and speaker connections, or use silver solder as another option.
However, silver is definitely a better conductor than tin. Although it oxidizes more easily than tin, silver oxide is as conductive as non oxidized silver.
I have no connection whatsoever with the company, but of note is the fact that Neutrik, the manufacturer of excellent connectors, uses silver for the contacts on all of its XLR and SpeakON connectors, except for the ones with gold contacts.
Here is an interesting article on tinned copper and skin effect of a signal:
http://www.belden.com/blog/broadcastav/in-defense-of-tinned-copper.cfm